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GATE 2015 : Life Sciences (Set h)

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GATE 2015 CHEMISTRY (COMPULSORY) XL-H H: CHEMISTRY (COMPULSORY) Q. 1 Q. 5 carry one mark each. Q.1 The molecule having net non-zero dipole moment is (A) CCl4 Q.2 (B) NF3 (C) CO2 (D) BCl3 The Diels-Alder adduct from the reaction between cyclopentadiene and benzyne is (A) (B) (C) (D) Q.3 The number of possible enantiomeric pair(s) in HOOC CH(OH) CH(OH) COOH is________ Q.4 For the electrochemical reaction, Cu (aq) + Zn(s) 2+ 2+ Cu(s) + Zn (aq) 37 the equilibrium constant at 25 oC is 1.7 10 . The change in standard Gibbs free energy ( Go) for this reaction at that temperature will be ________ kJ mol 1 (up to one decimal place). (Given: R = 8.314 JK 1mol 1) Q.5 Among the following diagrams, the one that correctly describes a zero order reaction (X product) is (Given: [X]o = initial concentration of reactant X; [X] = concentration of reactant X at time t and t1/2 = half-life period of reactant X) (A) (B) t1/2 1/[X] t (D) (C) t1/2 t1/2 1/[X]o XL-H [X]o [X]o 1/3

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